Silyl Ketene Acetal Chemistry: Steric Limitations in Lewis Acid-Promoted Addition of Ketones

Citation:

G. Wenke, Jacobsen, E. N., Totten, G. E., Karydas, A. C., and Rhodes, Y. E., “Silyl Ketene Acetal Chemistry: Steric Limitations in Lewis Acid-Promoted Addition of Ketones”, Synthetic Communications, vol. 13, no. 6, p. 449-458, 1983.

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E. N. Jacobsen, Zhang, W., Muci, A. R., Ecker, J. R., and Deng, L., “Highly Enantioselective Epoxidation Catalysts Derived from 1,2-Diaminocyclohexane”, Journal of the American Chemical Society, vol. 113, no. 18, p. 7063–7064, 1991.

W. Zhang and Jacobsen, E. N., “Asymmetric Epoxidation with Sodium Hypochlorite Catalyzed by Readily Available Chiral Mn(III) Salen Complexes”, Journal of Organic Chemistry, vol. 56, no. 7, p. 2296–2298, 1991.

W. Zhang and Jacobsen, E. N., “Preparation of trans-1,2-Diamino-1,2-Dimethylcyclohexane via Highly Stereoselective Olefin Oxidation by Dinitrogen Tetroxide”, Tetrahedron Letters, vol. 32, no. 14, p. 1711-1714, 1991.

W. Zhang, Loebach, J. L., Wilson, S. R., and Jacobsen, E. N., “Enantioselective Epoxidation of Unfunctionalized Olefins Catalyzed by (salen)Manganese Complexes”, Journal of the American Chemical Society, vol. 112, no. 7, p. 2801–2803, 1990.

J. S. Svendsen, Markó, I. E., Jacobsen, E. N., Pulla Rao, C., Bott, S., and Sharpless, K. B., “The structure of osmium tetraoxide-cinchona alkaloid complexes”, Journal of Organic Chemistry, vol. 54, no. 10, p. 2263–2264, 1989.

J. S. M. Wai, Markó, I. E., Svendsen, J. S., Finn, M. G., Jacobsen, E. N., and Sharpless, K. B., “A Mechanistic Insight Leads to a Greatly Improved Osmium-Catalyzed Asymmetric Dihydroxylation Process”, Journal of the American Chemical Society, vol. 111, no. 3, p. 1123–1125, 1989.

Eric N. Jacobsen

Department of Chemistry and Chemical Biology at Harvard University

Silyl Ketene Acetal Chemistry: Steric Limitations in Lewis Acid-Promoted Addition of Ketones

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