Li, J., Zhu, F., Liu, J., Dong, J., & Mao, W. L. (2020).
Reactive preservation of carbonate in Earth's mantle transition zone. In
C. E. Manning & J. - F. Lin (Ed.),
Carbon in Earth's Interior (pp. 167-177) . American Geophysical Union (AGU).
Publisher's VersionAbstractCalcium-rich carbonate may be preserved in fast-descending slabs to reach the mantle transition zone (MTZ), which is known to be at least locally hydrous. At MTZ pressures, the melting curve of CaCO3 crosses the geotherm and is further depressed by water; hence, Ca-rich carbonate may be mobilized by hydrous melting and escape the MTZ. Here we show that aragonite reacts with wadsleyite to produce magnesite under the pressure and temperature conditions of cold slabs in the MTZ. Water considerably enhances conversion of Ca-rich carbonate into more refractory magnesite, helping to retain carbonate in the deep mantle.
Daviau, K., Fischer, R. A., Brennan, M. C., Dong, J., Suer, T. ‐A., Couper, S., Meng, Y., et al. (2020).
Equation of state of TiN at high pressures and temperatures: A possible host for nitrogen in planetary mantles.
Journal of Geophysical Research: Solid Earth ,
126, e2020JB020074.
Publisher's VersionAbstractNitrogen, the most abundant element in Earth's atmosphere, is also a primary component of solid nitride minerals found in meteorites and on Earth's surface. If they remain stable to high pressures and temperatures, these nitrides may also be important reservoirs of nitrogen in planetary interiors. We used synchrotron X-ray diffraction to measure the thermal equation of state and phase stability of titanium nitride (TiN) in a laser-heated diamond anvil cell at pressures up to ∼70 GPa and temperatures up to ∼2,500 K. TiN maintains the cubic B1 (NaCl-type) crystal structure over the entire pressure and temperature range explored. It has K0 = 274 (4) GPa, K0′ = 3.9 (2), and γ0 = 1.39 (4) for a fixed V0 = 76.516 (30) Å3 (based on experimental measurements), q = 1, and θ0 = 579 K. Additionally, we collected Raman spectra of TiN up to ∼60 GPa, where we find that the transverse acoustic (TA), longitudinal acoustic (LA), and transverse optical phonon modes exhibit mode Grüneisen parameters of 1.66(17), 0.54(15), and 0.93 (4), respectively. Based on our equation of state, TiN has a density of ∼5.6–6.4 g/cm3 at Earth's lower mantle conditions, significantly more dense than both the mantle of the Earth and the estimated densities of the mantles of other terrestrial planets, but less dense than planetary cores. We find that TiN remains stable against physical decomposition at the pressures and temperatures found within Earth's mantle, making it a plausible reservoir for deep planetary nitrogen if chemical conditions allow its formation.
Zhou, D., Dong, J., Si, Y., Zhu, F., & Li, J. (2020).
Melting curve of potassium chloride from in situ ionic conduction measurements.
Minerals ,
10 (3), 250.
Publisher's VersionAbstractWe report experimental constraints on the melting curve of potassium chloride (KCl) between 3.2 and 9 GPa from in situ ionic conduction measurements using a multi-anvil apparatus. On the basis of concurrent measurements of KCl and sodium chloride (NaCl) at 1 bar using the differential thermal analysis (DTA) method and Pt sphere marker, we show that the peak rate of increase in ionic current with temperature upon heating coincides with latent heat ledge and fall of Pt sphere, thus establishing the criterion for melting detection from ionic conduction measurements. Applying this criterion to high pressures, we found that the melting point of KCl rose steeply with increasing pressure to exceed 2443 ± 100 K at 9 GPa. Fitting the results of this study together with existing data at pressures below 4 GPa and above 20 GPa, we obtained the Simon’s melting equation for KCl in the simple cubic B2 structure between 1.8 and 50 GPa: Tm=1323(P/1.872.2(1)+1)1/2.7(1) , where T is in K and P is in GPa. Starting at 1 bar, the melting point of KCl increases at an average rate of ~150 K/GPa to cross that of Pt near 9 GPa. The highly refractory nature of KCl makes it a sensitive pressure calibrant for the large-volume pressure at moderate pressures and a potential sample container for experiments at moderate pressures and very high temperatures.