Publications

2018
CP Goodrich, MP Brenner, and K Ribbeck. 2018. “Enhanced diffusion by binding to the crosslinks of a polymer gel.” Nature Communications, 9, Pp. 4348.Abstract
Creating a selective gel that filters particles based on their interactions is a major goal of nanotechnology, with far-reaching implications from drug delivery to controlling assembly pathways. However, this is particularly difficult when the particles are larger than the gel’s characteristic mesh size because such particles cannot passively pass through the gel. Thus, filtering requires the interacting particles to transiently reorganize the gel’s internal structure. While significant advances, e.g., in DNA engineering, have enabled the design of nano-materials with programmable interactions, it is not clear what physical principles such a designer gel could exploit to achieve selective permeability. We present an equilibrium mechanism where crosslink binding dynamics are affected by interacting particles such that particle diffusion is enhanced. In addition to revealing specific design rules for manufacturing selective gels, our results have the potential to explain the origin of selective permeability in certain biological materials, including the nuclear pore complex.
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2017
JP Sethna, MK Bierbaum, KA Dahmen, CP Goodrich, JR Greer, LX Hayden, JP Kent-Dobias, ED Lee, DB Liarte, X Ni, KN Quinn, A Raju, DZ Rocklin, A Shekhawat, and S Zapperi. 2017. “Deformation of Crystals: Connections with Statistical Physics.” Annu. Rev. Mater. Res., 47, Pp. 217.Abstract

We give a bird’s-eye view of the plastic deformation of crystals aimed at the statistical physics community, and a broad introduction into the statistical theories of forced rigid systems aimed at the plasticity community. Memory effects in magnets, spin glasses, charge density waves, and dilute colloidal suspensions are discussed in relation to the onset of plastic yielding in crystals. Dislocation avalanches and complex dislocation tangles are discussed via a brief introduction to the renormalization group and scaling. Analogies to emergent scale invariance in fracture, jamming, coarsening, and a variety of depinning transitions are explored. Dislocation dynamics in crystals challenges nonequilibrium statistical physics. Statistical physics provides both cautionary tales of subtle memory effects in nonequilibrium systems, and systematic tools designed to address complex scale-invariant behavior on multiple length and time scales.

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JW Rocks, N Pashine, I Bischofberger, CP Goodrich, A. J. Liu, and SR Nagel. 2017. “Designing allostery-inspired response in mechanical networks.” Proc. Nat. Acad. Sci., 114, Pp. 2520.Abstract
Recent advances in designing metamaterials have demonstrated that global mechanical properties of disordered spring networks can be tuned by selectively modifying only a small subset of bonds. Here, using a computationally efficient approach, we extend this idea to tune more general properties of networks. With nearly complete success, we are able to produce a strain between any two target nodes in a network in response to an applied source strain on any other pair of nodes by removing only ∼1% of the bonds. We are also able to control multiple pairs of target nodes, each with a different individual response, from a single source, and to tune multiple independent source/target responses simultaneously into a network. We have fabricated physical networks in macroscopic 2D and 3D systems that exhibit these responses. This work is inspired by the long-range coupled conformational changes that constitute allosteric function in proteins. The fact that allostery is a common means for regulation in biological molecules suggests that it is a relatively easy property to develop through evolution. In analogy, our results show that long-range coupled mechanical responses are similarly easy to achieve in disordered networks.
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M Baity-Jesi, CP Goodrich, A. J. Liu, SR Nagel, and JP Sethna. 2017. “Emergent SO(3) Symmetry of the Frictionless Shear Jamming Transition.” J Stat Phys, 167, Pp. 217.Abstract

We study the shear jamming of athermal frictionless soft spheres, and find that in the thermodynamic limit, a shear-jammed state exists with different elastic properties from the isotropically-jammed state. For example, shear-jammed states can have a non-zero residual shear stress in the thermodynamic limit that arises from long-range stress-stress correlations. As a result, the ratio of the shear and bulk moduli, which in isotropically-jammed systems vanishes as the jamming transition is approached from above, instead approaches a constant. Despite these striking differences, we argue that in a deeper sense, the shear jamming and isotropic jamming transitions actually have the same symmetry, and that the differences can be fully understood by rotating the six-dimensional basis of the elastic modulus tensor.

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CP Goodrich and MP Brenner. 2017. “Using active colloids as machines to weave and braid on the micrometer scale.” PNAS, 114, 2, Pp. 257-262.Abstract

Controlling motion at the microscopic scale is a fundamental goal in the development of biologically inspired systems. We show that the motion of active, self-propelled colloids can be sufficiently controlled for use as a tool to assemble complex structures such as braids and weaves out of microscopic filaments. Unlike typical self-assembly paradigms, these structures are held together by geometric constraints rather than adhesive bonds. The out-of-equilibrium assembly that we propose involves precisely controlling the 2D motion of active colloids so that their path has a nontrivial topology. We demonstrate with proof-of-principle Brownian dynamics simulations that, when the colloids are attached to long semiflexible filaments, this motion causes the filaments to braid. The ability of the active particles to provide sufficient force necessary to bend the filaments into a braid depends on a number of factors, including the self-propulsion mechanism, the properties of the filament, and the maximum curvature in the braid. Our work demonstrates that nonequilibrium assembly pathways can be designed using active particles.

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2016
J. M. Rieser, CP Goodrich, A. J. Liu, and D. J. Durian. 2016. “Divergence of Voronoi Cell Anisotropy Vector: A Threshold-Free Characterization of Local Structure in Amorphous Materials.” Phys. Rev. Lett., 116, Pp. 088001.Abstract

Characterizing structural inhomogeneity is an essential step in understanding the mechanical response of amorphous materials. We introduce a threshold-free measure based on the field of vectors pointing from the center of each particle to the centroid of the Voronoi cell in which the particle resides. These vectors tend to point in toward regions of high free volume and away from regions of low free volume, reminiscent of sinks and sources in a vector field. We compute the local divergence of these vectors, where positive values correspond to overpacked regions and negative values identify underpacked regions within the material. Distributions of this divergence are nearly Gaussian with zero mean, allowing for structural characterization using only the moments of the distribution. We explore how the standard deviation and skewness vary with the packing fraction for simulations of bidisperse systems and find a kink in these moments that coincides with the jamming transition.

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R Lombardini, R Acevedo, A Kuczala, KP Keys, CP Goodrich, and BR Johnson. 2016. “Higher-order wavelet reconstruction/differentiation filters and Gibbs phenomena.” Journal of Computational Physics, 305, Pp. 244 - 262.Abstract

Abstract An orthogonal wavelet basis is characterized by its approximation order, which relates to the ability of the basis to represent general smooth functions on a given scale. It is known, though perhaps not widely known, that there are ways of exceeding the approximation order, i.e., achieving higher-order error in the discretized wavelet transform and its inverse. The focus here is on the development of a practical formulation to accomplish this first for 1D smooth functions, then for 1D functions with discontinuities and then for multidimensional (here 2D) functions with discontinuities. It is shown how to transcend both the wavelet approximation order and the 2D Gibbs phenomenon in representing electromagnetic fields at discontinuous dielectric interfaces that do not simply follow the wavelet-basis grid.

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AL Graves, S Nashed, E Padgett, CP Goodrich, AJ Liu, and JP Sethna. 2016. “Pinning Susceptibility: The Effect of Dilute, Quenched Disorder on Jamming.” Phys. Rev. Lett., 116, Pp. 235501. pdf
CP Goodrich, A. J. Liu, and JP Sethna. 2016. “Scaling ansatz for the jamming transition.” PNAS, 113, 35, Pp. 9745-9750.Abstract

We propose a Widom-like scaling ansatz for the critical jamming transition. Our ansatz for the elastic energy shows that the scaling of the energy, compressive strain, shear strain, system size, pressure, shear stress, bulk modulus, and shear modulus are all related to each other via scaling relations, with only three independent scaling exponents. We extract the values of these exponents from already known numerical or theoretical results, and we numerically verify the resulting predictions of the scaling theory for the energy and residual shear stress. We also derive a scaling relation between pressure and residual shear stress that yields insight into why the shear and bulk moduli scale differently. Our theory shows that the jamming transition exhibits an emergent scale invariance, setting the stage for the potential development of a renormalization group theory for jamming.

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See Commentary by Srikanth Sastry

DM Sussman, CP Goodrich, and A. J. Liu. 2016. “Spatial structure of states of self stress in jammed systems.” Soft Matter, 12, Pp. 3982-3990.Abstract

States of self stress, organizations of internal forces in many-body systems that are in equilibrium with an absence of external forces, can be thought of as the constitutive building blocks of the elastic response of a material. In overconstrained disordered packings they have a natural mathematical correspondence with the zero-energy vibrational modes in underconstrained systems. While substantial attention in the literature has been paid to diverging length scales associated with zero- and finite-energy vibrational modes in jammed systems, less is known about the spatial structure of the states of self stress. In this work we define a natural way in which a unique state of self stress can be associated with each bond in a disordered spring network derived from a jammed packing, and then investigate the spatial structure of these bond-localized states of self stress. This allows for an understanding of how the elastic properties of a system would change upon changing the strength or even existence of any bond in the system.

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2015
R van Drongelen, A Pal, CP Goodrich, and T Idema. 2015. “Collective dynamics of soft active particles.” Phys. Rev. E, 91, Pp. 032706.Abstract

We present a model of soft active particles that leads to a rich array of collective behavior found also in dense biological swarms of bacteria and other unicellular organisms. Our model uses only local interactions, such as Vicsek-type nearest-neighbor alignment, short-range repulsion, and a local boundary term. Changing the relative strength of these interactions leads to migrating swarms, rotating swarms, and jammed swarms, as well as swarms that exhibit run-and-tumble motion, alternating between migration and either rotating or jammed states. Interestingly, although a migrating swarm moves slower than an individual particle, the diffusion constant can be up to three orders of magnitude larger, suggesting that collective motion can be highly advantageous, for example, when searching for food.

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DM Sussman, CP Goodrich, A. J. Liu, and SR Nagel. 2015. “Disordered surface vibrations in jammed sphere packings.” Soft Matter, 11, Pp. 2745-2751.Abstract

We study the vibrational properties near a free surface of disordered spring networks derived from jammed sphere packings. In bulk systems, without surfaces, it is well understood that such systems have a plateau in the density of vibrational modes extending down to a frequency scale [small omega]*. This frequency is controlled by [capital Delta]Z = ?Z? - 2d, the difference between the average coordination of the spheres and twice the spatial dimension, d, of the system, which vanishes at the jamming transition. In the presence of a free surface we find that there is a density of disordered vibrational modes associated with the surface that extends far below [small omega]*. The total number of these low-frequency surface modes is controlled by [capital Delta]Z, and the profile of their decay into the bulk has two characteristic length scales, which diverge as [capital Delta]Z-1/2 and [capital Delta]Z-1 as the jamming transition is approached.

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CP Goodrich, A. J. Liu, and SR Nagel. 2015. “The Principle of Independent Bond-Level Response: Tuning by Pruning to Exploit Disorder for Global Behavior.” Phys. Rev. Lett., 114, Pp. 225501.Abstract

We introduce a principle unique to disordered solids wherein the contribution of any bond to one global perturbation is uncorrelated with its contribution to another. Coupled with sufficient variability in the contributions of different bonds, this ?independent bond-level response? paves the way for the design of real materials with unusual and exquisitely tuned properties. To illustrate this, we choose two global perturbations: compression and shear. By applying a bond removal procedure that is both simple and experimentally relevant to remove a very small fraction of bonds, we can drive disordered spring networks to both the incompressible and completely auxetic limits of mechanical behavior.

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2014
CP Goodrich, A. J. Liu, and SR Nagel. 2014. “Comment on "Repulsive Contact Interactions Make Jammed Particulate Systems Inherently Nonharmonic''.” Phys. Rev. Lett., 112, Pp. 049801. pdf
CP Goodrich, AJ Liu, and SR Nagel. 2014. “Contact nonlinearities and linear response in jammed particulate packings.” Phys. Rev. E, 90, Pp. 022201.Abstract

Packings of frictionless athermal particles that interact only when they overlap experience a jamming transition as a function of packing density. Such packings provide the foundation for the theory of jamming. This theory rests on the observation that, despite the multitude of disordered configurations, the mechanical response to linear order depends only on the distance to the transition. We investigate the validity and utility of such measurements that invoke the harmonic approximation and show that, despite particles coming in and out of contact, there is a well-defined linear regime in the thermodynamic limit.

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CP Goodrich, S Dagois-Bohy, BP Tighe, M van Hecke, A. J. Liu, and SR Nagel. 2014. “Jamming in finite systems: Stability, anisotropy, fluctuations, and scaling.” Phys. Rev. E, 90, Pp. 022138.Abstract

Athermal packings of soft repulsive spheres exhibit a sharp jamming transition in the thermodynamic limit. Upon further compression, various structural and mechanical properties display clean power-law behavior over many decades in pressure. As with any phase transition, the rounding of such behavior in finite systems close to the transition plays an important role in understanding the nature of the transition itself. The situation for jamming is surprisingly rich: the assumption that jammed packings are isotropic is only strictly true in the large-size limit, and finite-size has a profound effect on the very meaning of jamming. Here, we provide a comprehensive numerical study of finite-size effects in sphere packings above the jamming transition, focusing on stability as well as the scaling of the contact number and the elastic response.

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T Still, CP Goodrich, K. Chen, PJ Yunker, S Schoenholz, A. J. Liu, and AG Yodh. 2014. “Phonon dispersion and elastic moduli of two-dimensional disordered colloidal packings of soft particles with frictional interactions.” Phys. Rev. E, 89, Pp. 012301.Abstract

Particle tracking and displacement covariance matrix techniques are employed to investigate the phonon dispersion relations of two-dimensional colloidal glasses composed of soft, thermoresponsive microgel particles whose temperature-sensitive size permits in situ variation of particle packing fraction. Bulk, B, and shear, G, moduli of the colloidal glasses are extracted from the dispersion relations as a function of packing fraction, and variation of the ratio G/B with packing fraction is found to agree quantitatively with predictions for jammed packings of frictional soft particles. In addition, G and B individually agree with numerical predictions for frictional particles. This remarkable level of agreement enabled us to extract an energy scale for the interparticle interaction from the individual elastic constants and to derive an approximate estimate for the interparticle friction coefficient.

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CP Goodrich, A. J. Liu, and SR Nagel. 2014. “Solids between the mechanical extremes of order and disorder.” Nature Physics, 10, Pp. 578–581.Abstract

For more than a century, physicists have described real solids in terms of perturbations about perfect crystalline order. Such an approach takes us only so far: a glass, another ubiquitous form of rigid matter, cannot be described in any meaningful sense as a defected crystal. Is there an opposite extreme to a crystal—a solid with complete disorder—that forms an alternative starting point for understanding real materials? Here, we argue that the solid comprising particles with finite-ranged interactions at the jamming transition constitutes such a limit. It has been shown that the physics associated with this transition can be extended to interactions that are long ranged. We demonstrate that jamming physics is not restricted to amorphous systems, but dominates the behaviour of solids with surprisingly high order. Just as the free-electron and tight-binding models represent two idealized cases from which to understand electronic structure, we identify two extreme limits of mechanical behaviour. Thus, the physics of jamming can be set side by side with the physics of crystals to provide an organizing structure for understanding the mechanical properties of solids over the entire spectrum of disorder.

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Featured in PennNews and Materials360 
See also accompanying News and Views by Giulio Biroli

MA Lohr, T Still, R Ganti, MD Gratale, ZS Davidson, KB Aptowicz, CP Goodrich, DM Sussman, and AG Yodh. 2014. “Vibrational and structural signatures of the crossover between dense glassy and sparse gel-like attractive colloidal packings.” Phys. Rev. E, 90, Pp. 062305.Abstract

We investigate the vibrational modes of quasi-two-dimensional disordered colloidal packings of hard colloidal spheres with short-range attractions as a function of packing fraction. Certain properties of the vibrational density of states (vDOS) are shown to correlate with the density and structure of the samples (i.e., in sparsely versus densely packed samples). Specifically, a crossover from dense glassy to sparse gel-like states is suggested by an excess of phonon modes at low frequency and by a variation in the slope of the vDOS with frequency at low frequency. This change in phonon mode distribution is demonstrated to arise largely from localized vibrations that involve individual and/or small clusters of particles with few local bonds. Conventional order parameters and void statistics did not exhibit obvious gel-glass signatures as a function of volume fraction. These mode behaviors and accompanying structural insights offer a potentially new set of indicators for identification of glass-gel transitions and for assignment of gel-like versus glass-like character to a disordered solid material.

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2013
CP Goodrich, WG Ellenbroek, and AJ Liu. 2013. “Stability of jammed packings I: the rigidity length scale.” Soft Matter, 9, 46, Pp. 10993.Abstract

In 2005, Wyart et al. [Europhys. Lett., 2005, 72, 486] showed that the low frequency vibrational properties of jammed amorphous sphere packings can be understood in terms of a length scale, called \(\ell^*\), that diverges as the system becomes marginally unstable. Despite the tremendous success of this theory, it has been difficult to connect the counting argument that defines \(\ell^*\) to other length scales that diverge near the jamming transition. We present an alternate derivation of \(\ell^*\) based on the onset of rigidity. This phenomenological approach reveals the physical mechanism underlying the length scale and is relevant to a range of systems for which the original argument breaks down. It also allows us to present the first direct numerical measurement of \(\ell^*\).

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