Publications

2019
Lu, X., L. Zhang, T. Wu, M. S. Long, J. Wang, D.J. Jacob, F. Zhang, et al.Development of the global atmospheric general circulation-chemistry model BCC-GEOS-Chem v1.0: model description and evaluation.” Geoscientific Model Development Discussions 2019 (2019): 1–39. Publisher's Version
Chance, K., X. Liu, C. Chan Miller, G. González Abad, G. Huang, C. Nowlan, A. Souri, et al.TEMPO Green Paper: Chemistry, physics, and meteorology experiments with the Tropospheric Emissions: monitoring of pollution instrument.” In Sensors, Systems, and Next-Generation Satellites XXIII, edited by Steven P. Neeck, Philippe Martimort, and Toshiyoshi Kimura, 11151:56 – 67. International Society for Optics and Photonics, 2019. Publisher's Version
Shen, Lu, Daniel J. Jacob, Lei Zhu, Qiang Zhang, Bo Zheng, Melissa P. Sulprizio, Ke Li, et al.The 2005–2016 Trends of Formaldehyde Columns Over China Observed by Satellites: Increasing Anthropogenic Emissions of Volatile Organic Compounds and Decreasing Agricultural Fire Emissions.” Geophysical Research Letters 46, no. 8 (2019): 4468-4475. Publisher's VersionAbstract
Abstract We use 2005–2016 observations of formaldehyde (HCHO) columns over China from the OMI, GOME-2, and SCIAMACHY satellite instruments to evaluate long-term trends in emission inventories of volatile organic compounds (VOCs) that affect air quality. The observations show large increases over 2005–2016 in the North China Plain (+1.1 ± 0.5% a−1 relative to 2005) and the Yangtze River Delta region (+1.5 ± 0.4% a−1 relative to 2005), consistent with the trend of anthropogenic VOC emissions in the Multi-resolution Emission Inventory for China (MEIC). Unlike other pollutants, VOC emissions have not been decreasing in recent years. An exception is the Huai River Basin in rural eastern China where the satellite data show rapidly decreasing VOC emissions since the early 2010s that appear to reflect bans on agricultural fires.
Zhu, L., D.J. Jacob, S. D. Eastham, M.P. Sulprizio, X. Wang, T. Sherwen, M. J. Evans, et al.Effect of sea salt aerosol on tropospheric bromine chemistry.” Atmospheric Chemistry and Physics 19, no. 9 (2019): 6497–6507. Publisher's Version
Song, S., M. Gao, W. Xu, Y. Sun, D. R. Worsnop, J. T. Jayne, Y. Zhang, et al.Possible heterogeneous chemistry of hydroxymethanesulfonate (HMS) in northern China winter haze.” Atmospheric Chemistry and Physics 19, no. 2 (2019): 1357–1371. Publisher's Version
Wang, X., D.J. Jacob, S. D. Eastham, M.P. Sulprizio, L. Zhu, Q. Chen, B. Alexander, et al.The role of chlorine in global tropospheric chemistry.” Atmospheric Chemistry and Physics 19, no. 6 (2019): 3981–4003. Publisher's Version
Zhang, Yuzhong, Ritesh Gautam, Daniel Zavala-Araiza, Daniel J. Jacob, Ruixiong Zhang, Lei Zhu, Jian-Xiong Sheng, and Tia Scarpelli. “Satellite-Observed Changes in Mexico's Offshore Gas Flaring Activity Linked to Oil/Gas Regulations.” Geophysical Research Letters 46, no. 3 (2019): 1879-1888. Publisher's VersionAbstract
Abstract Gas flaring is a commonly used practice in the oil and gas sector that leads to key air pollutant and greenhouse gas emissions. Here we use multipollutant (NO2, SO2) satellite observations from 2005 to 2017 to quantify gas flaring activity in Mexico's offshore production cluster, which produces  50–70% of the country's oil and is among the world's largest oil fields. We estimate annual flared gas volume ranging from 5.5 to 20 × 109 m3 over the Mexican offshore corresponding to >40% associated gas production, which is significantly larger than for instance offshore United States where reportedly <3% of associated gas is flared. The 13-year record of satellite-derived gas flaring indicates a drastic increase until 2008 and a decline afterward. While the increased flaring is associated with efforts to enhance oil production, the post-2008 decline is linked to an expanding capacity of associated gas utilization, providing a continuing opportunity to reduce flaring for environmental and economic benefits.
2018
Sun, K., L. Zhu, K. Cady-Pereira, C. Chan Miller, K. Chance, L. Clarisse, P.-F. Coheur, et al.A physics-based approach to oversample multi-satellite, multi-species observations to a common grid.” Atmospheric Measurement Techniques Discussions 2018 (2018): 1–30. Publisher's Version
Kaiser, J., D.J. Jacob, L. Zhu, K. R. Travis, J. A. Fisher, G. González Abad, L. Zhang, et al.High-resolution inversion of OMI formaldehyde columns to quantify isoprene emission on ecosystem-relevant scales: application to the southeast US.” Atmospheric Chemistry and Physics 18, no. 8 (2018): 5483–5497. Publisher's Version
2017
Zhu, Lei, Loretta J. Mickley, Daniel J. Jacob, Eloïse A. Marais, Jianxiong Sheng, Lu Hu, Gonzalo González Abad, and Kelly Chance. “Long-term (2005–2014) trends in formaldehyde (HCHO) columns across North America as seen by the OMI satellite instrument: Evidence of changing emissions of volatile organic compounds.” Geophysical Research Letters 44, no. 13 (2017): 7079–7086. Publisher's Version
Chan Miller, C., D.J. Jacob, E. A. Marais, K. Yu, K. R. Travis, P. S. Kim, J. A. Fisher, et al.Glyoxal yield from isoprene oxidation and relation to formaldehyde: chemical mechanism, constraints from SENEX aircraft observations, and interpretation of OMI satellite data.” Atmospheric Chemistry and Physics 17, no. 14 (2017): 8725–8738. Publisher's Version
Zhu, Lei, Daniel J. Jacob, Frank N. Keutsch, Loretta J. Mickley, Richard Scheffe, Madeleine Strum, Gonzalo González Abad, et al.Formaldehyde (HCHO) As a Hazardous Air Pollutant: Mapping Surface Air Concentrations from Satellite and Inferring Cancer Risks in the United States.” Environmental Science & Technology 51, no. 10 (2017): 5650-5657. Publisher's Version
2016
Travis, K. R., D.J. Jacob, J. A. Fisher, P. S. Kim, E. A. Marais, L. Zhu, K. Yu, et al.Why do models overestimate surface ozone in the Southeast United States?Atmospheric Chemistry and Physics 16, no. 21 (2016): 13561–13577. Publisher's Version
Zhu, L., D.J. Jacob, P. S. Kim, J. A. Fisher, K. Yu, K. R. Travis, L.J. Mickley, et al.Observing atmospheric formaldehyde (HCHO) from space: validation and intercomparison of six retrievals from four satellites (OMI, GOME2A, GOME2B, OMPS) with SEAC⁴RS aircraft observations over the southeast US.” Atmospheric Chemistry and Physics 16, no. 21 (2016): 13477–13490. Publisher's Version
Fisher, J. A., D.J. Jacob, K. R. Travis, P. S. Kim, E. A. Marais, C. Chan Miller, K. Yu, et al.Organic nitrate chemistry and its implications for nitrogen budgets in an isoprene- and monoterpene-rich atmosphere: constraints from aircraft (SEAC4RS) and ground-based (SOAS) observations in the Southeast US.” Atmospheric Chemistry and Physics 16, no. 9 (2016): 5969–5991. Publisher's Version
Yu, K., D.J. Jacob, J. A. Fisher, P. S. Kim, E. A. Marais, C. C. Miller, K. R. Travis, et al.Sensitivity to grid resolution in the ability of a chemical transport model to simulate observed oxidant chemistry under high-isoprene conditions.” Atmospheric Chemistry and Physics 16, no. 7 (2016): 4369–4378. Publisher's Version
Marais, E. A., D.J. Jacob, J. L. Jimenez, P. Campuzano-Jost, D. A. Day, W. Hu, J. Krechmer, et al.Aqueous-phase mechanism for secondary organic aerosol formation from isoprene: application to the southeast United States and co-benefit of SO2 emission controls.” Atmospheric Chemistry and Physics 16, no. 3 (2016): 1603–1618. Publisher's Version
2015
Kim, P. S., D.J. Jacob, J. A. Fisher, K. Travis, K. Yu, L. Zhu, R. M. Yantosca, et al.Sources, seasonality, and trends of southeast US aerosol: an integrated analysis of surface, aircraft, and satellite observations with the GEOS-Chem chemical transport model.” Atmospheric Chemistry and Physics 15, no. 18 (2015): 10411–10433. Publisher's Version
2014
Zhu, Lei, Daniel J Jacob, Loretta J Mickley, Eloïse A Marais, Daniel S Cohan, Yasuko Yoshida, Bryan N Duncan, Gonzalo González Abad, and Kelly V Chance. “Anthropogenic emissions of highly reactive volatile organic compounds in eastern Texas inferred from oversampling of satellite (OMI) measurements of HCHO columns.” Environmental Research Letters 9, no. 11 (2014): 114004. Publisher's VersionAbstract
Satellite observations of formaldehyde (HCHO) columns provide top-down constraints on emissions of highly reactive volatile organic compounds (HRVOCs). This approach has been used previously in the US to estimate isoprene emissions from vegetation, but application to anthropogenic emissions has been stymied by lack of a discernable HCHO signal. Here we show that temporal oversampling of HCHO data from the Ozone Monitoring Instrument (OMI) for 2005–2008 enables detection of urban and industrial plumes in eastern Texas including Houston, Port Arthur, and Dallas/Fort Worth. By spatially integrating the HCHO enhancement in the Houston plume observed by OMI we estimate an anthropogenic HCHO source of 250 ± 140 kmol h −1 . This implies that anthropogenic HRVOC emissions in Houston are 4.8 ± 2.7 times higher than reported by the US Environmental Protection Agency inventory, and is consistent with field studies identifying large ethene and propene emissions from petrochemical industrial sources.

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